[사이테크 플러스] Development of high-efficiency next-generation solar cell materials… Publication of the cover paper for’Nature’

Chemical Research Team improves efficiency of electron transport layer and perovskite layer… “1㎠ device efficiency 23%”

(Seoul = Yonhap News) Reporter Lee Ju-young = Korean researchers developed a core material that can dramatically increase the efficiency of perovskite solar cells, which are attracting attention as next-generation solar cells, and photoelectric conversion of 23%, the world’s highest level in 1㎠ devices. Achieved efficiency.

Dr. Jang-won Seo of the Korea Research Institute of Chemical Technology is giving a briefing on the'Development of Ultra High Efficiency Perovskite Solar Cell Material' in the press room of the Ministry of Science and ICT on the 23rd. [과학기술정보통신부 제공. 재판매 및 DB 금지]

Dr. Jang-won Seo of the Korea Research Institute of Chemical Technology is giving a briefing on the’Development of Ultra High Efficiency Perovskite Solar Cell Material’ in the press room of the Ministry of Science and ICT on the 23rd. [과학기술정보통신부 제공. 재판매 및 DB 금지]

Dr. Jang-won Seo’s team at the Korea Research Institute of Chemical Technology announced on the 25th that it has dramatically improved efficiency by developing a new material for the electron transport layer that can increase the voltage and a new material for the perovskite layer that can increase the current among the layers that make up the perovskite solar cell. .

The results of this study were published in the international academic journal’Nature’ as the cover paper on the day.

Perovskite is a material with a special structure that exhibits nonconductor, semiconductor, conductor properties and superconductivity, and can be easily manufactured by a low-temperature solution process using inexpensive chemical materials, and has been attracting attention as a candidate for the next generation solar cell to replace the existing silicon solar cell. .

However, perovskite solar cells still have many challenges to overcome for industrialization, such as lower photoelectric conversion efficiency for converting light into electricity than conventional silicon solar cells, and increasing stability for long-term use in real environments.

Perovskite solar cell photo (left) and structure
Perovskite solar cell photo (left) and structure

The perovskite layer material absorbs light and is divided into electrons and holes, and electricity is generated by moving the electron transport layer and the hole transport layer, respectively, to the electrode.[한국화학연구원 제공. 재판매 및 DB 금지]

In this study, the research team developed an electron transport layer material and a perovskite layer material that affect voltage and current in order to increase the efficiency of perovskite solar cells.

An electron transport layer material with reduced defects preventing electron transport (transport) was made by a chemical solution evaporation method that directly synthesizes tin oxide (SnO₂) on the transparent electrode, which is a solar cell, to form an electron transport layer, thereby increasing the voltage of the battery.

In addition, it increased the current by developing a method of synthesizing a perovskite layer material that can absorb more light. The perovskite layer composed of a perovskite crystal structure contains black crystals that absorb light well and yellow crystals that do not absorb light well. It was made to absorb light well.

Perovskite thin film synthesized by additives and surface treatment process (a), perovskite solar cell efficiency made of perovskite thin film with improved properties (b), 25.2% certification efficiency recorded in the NREL efficiency chart ( c, September 2019) [한국화학연구원 제공. 재판매 및 DB 금지]

Perovskite thin film synthesized by additives and surface treatment process (a), perovskite solar cell efficiency made of perovskite thin film with improved properties (b), 25.2% certification efficiency recorded in the NREL efficiency chart ( c, September 2019) [한국화학연구원 제공. 재판매 및 DB 금지]

The research team reported that the perovskite solar cell made of these materials recorded the highest efficiency officially certified by the National Renewable Energy Research Institute (NREL) at the time in September 2019 with a photoelectric conversion efficiency of 25.2% at 0.1㎠. He explained that it achieved the world’s highest efficiency at 23%, showing the possibility of large area.

The luminous efficiency, which is one of the indicators of the excellence of solar cell efficiency, recorded 17%, which is much higher than the existing perovskite solar cell, which is 5-10%, and proved for the first time that it can be applied to displays as well as the field of renewable energy. Added.

Dr. Jang-Won Seo said, “Efficiency of 25% or more is equivalent to 80.5% of the theoretical maximum efficiency of perovskite solar cells. If further efficiency improvement is achieved, more than 26% efficiency is possible, so the highest efficiency of existing silicon solar cells (26.7 %).”

'Nature' cover paper image
‘Nature’ cover paper image

[한국화학연구원 제공. 재판매 및 DB 금지]

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